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Update sample introduction terms (#465)
* update sample introduction term definitions - MS:1000058 (flow injection analysis): clarify as discrete aliquot injection into carrier stream producing transient signal; add FIA, FIA-MS synonyms - MS:1000060 (infusion): clarify as continuous delivery; add direct infusion, DIMS synonyms - MS:1000249 (direct liquid introduction): clarify as legacy LC-MS interface with flow splitting, superseded by API methods * remove 'FIA-MS, DIMS acronyms & 'chromatographic' removed from FIA/DI defs --------- Co-authored-by: Joshua Klein <mobiusklein@gmail.com>
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psi-ms.obo

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format-version: 1.2
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data-version: 4.1.228
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date: 02:12:2025 11:00
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saved-by: Joshua Klein
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data-version: 4.1.229
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date: 15:01:2026 12:00
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saved-by: Jonathan Hunter
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default-namespace: MS
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namespace-id-rule: * MS:$sequence(7,0,9999999)$
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namespace-id-rule: * PEFF:$sequence(7,0,9999999)$
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[Term]
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id: MS:1000058
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name: flow injection analysis
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def: "Sample is directly injected or infused into the ionization source." [PSI:MS]
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def: "A sample introduction method in which a discrete sample aliquot is injected into a continuous carrier solvent stream and transported to the ionization source without separation, producing a transient analytical signal." [PSI:MS]
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synonym: "FIA" EXACT []
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is_a: MS:1000007 ! inlet type
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[Term]
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[Term]
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id: MS:1000060
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name: infusion
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def: "The continuous flow of solution of a sample into the ionization source." [PSI:MS]
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def: "A sample introduction method in which a sample solution is continuously delivered to the ionization source at a constant flow rate without separation." [PSI:MS]
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synonym: "direct infusion" EXACT []
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is_a: MS:1000007 ! inlet type
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[Term]
@@ -1899,7 +1901,7 @@ is_a: MS:1000007 ! inlet type
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[Term]
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id: MS:1000249
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name: direct liquid introduction
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def: "The delivery of a liquid sample into a mass spectrometer for spray or desorption ionization." [PSI:MS]
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def: "A legacy liquid chromatography-mass spectrometry interface in which a minor fraction of the eluate flow is split and introduced through a narrow orifice or diaphragm directly into the ion source, with solvent-mediated chemical ionization. This interface was largely superseded by atmospheric pressure ionization methods." [PSI:MS]
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synonym: "DLI" EXACT []
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is_a: MS:1000007 ! inlet type
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